核电应急柴油发电机组滑油低压保护停机控制的设计优化

通过采用转速分段及增加短延时的改进方法，对当前核电应急柴油发电机组滑油低压保护停机控制设计进行了优化。经论证与试验表明:优化后的保护停机控制对机组起动及运行过程均起到了保护作用，同时确保了滑油压力的正常建立，避免了机组因受外部因素影响导致应急保护停机误动作，提高了机组起动的可靠性。该优化方案已经在核电厂应急柴油发电机组控制系统中得到广泛应用。     

寒冷地区用空气源热泵热水器准双级压缩循环特性研究

空气源热泵热水器在寒冷地区运行时会出现排气温度过高、制热性能弱等弊端,准双级压缩循环技术可有效改善其在寒冷地区的运行特性。采用带中压补气的转子压缩机,研制了以R410A为循环工质的空气源热泵热水器,试验研究了系统在寒冷地区低温环境下的制热性能。结果表明:带中压补气的空气源热泵热水器系统排气温度较无补气有所降低,当室外温度从7.0下降到-25.0℃时,与无补气系统相比,补气系统制热量提升了6.2%～15.5%,压缩机功率提升了2.8%～9.5%,COP_h提升了3.3%～9.6%。     

浅谈船用主机使用低硫燃油面临的挑战与应对措施

介绍了低硫燃油和传统的船用高硫燃油在化学成分和物理特性方面存在的诸多不同;指出:IMO2020限硫令对船舶运营带来了很大的挑战。基于两大主机制造商的相关文件和实际服务经验，归纳总结了船用主机使用低硫燃油运营时应注意的事项及应对措施，为船舶安全稳定运营提供参考。     

低速机机架贯穿螺栓设计计算分析

采用ANSA和ANSYS联合对某低速机贯穿螺栓进行建模仿真,探讨了不同工况下,该贯穿螺栓的应力水平和应力幅值变化。结果表明:各贯穿螺栓由于安装位置不同,所受应力幅值也不尽相同;并呈现两端大,中间小的特点。为贯穿螺栓的优化设计提供了参考。     

Clustering biomedical and gene expression datasets with kernel density and unique neighborhood set based vein detection

It is a crucial need for a clustering technique to produce high-quality clusters from biomedical and gene expression datasets without requiring any user inputs. Therefore, in this paper we present a clustering technique called KUVClust that produces high-quality clusters when applied on biomedical and gene expression datasets without requiring any user inputs. The KUVClust algorithm uses three concepts namely multivariate kernel density estimation, unique closest neighborhood set and vein-based clustering. Although these concepts are known in the literature, KUVClust combines the concepts in a novel manner to achieve high-quality clustering results. The performance of KUVClust is compared with established clustering techniques on real-world biomedical and gene expression datasets. The comparisons were evaluated in terms of three criteria (purity, entropy, and sum of squared error (SSE)). Experimental results demonstrated the superiority of the proposed technique over the existing techniques for clustering both the low dimensional biomedical and high dimensional gene expressions datasets used in the experiments.     

Halogenation effect promoted low bandgap polymers based on asymmetric isoindigo unit with low energy loss

To optimize the energy levels of the structural framework of isoindigo polymers, a series of asymmetric isoindigo based low bandgap polymers with chlorine, fluorine and thiazole substituents was constructed and their optical, electrochemical and photovoltaic properties were comparatively evaluated for the impact of different substitutions. In comparison with the polymer based on 2,2'‐bithiophene and isoindigo unit (PTi) with non‐substituted bithiophene as the donor moiety, the highest occupied molecular orbital energy level for the newly synthesized polymers is significantly decreased, and in turn an improvement of the open‐circuit voltage (V_OC) is noted in the corresponding photovoltaic devices. More importantly, combined with a low bandgap of 1.32 eV, the energy losses (E_loss) could be reduced to 0.61 eV for polymer based on chlorinated 2,2'‐bithiophene and isoindigo unit (PCl). In addition, the halogen moieties are observed to be superior in device fabrication and give better values than the thiazole substituent. Both fluorinated and chlorinated polymer donors exhibited improved performance compared with the original polymer PTi. Consequently, this work not only presents the influence of different electron withdrawing substituents on the physicochemical and photovoltaic performance, but also backs the concept of how to reduce the energy loss via the heteroatom effect. © 2020 Society of Chemical Industry     

Novel low‐dielectric‐constant fluorine‐functionalized polysulfone with outstanding comprehensive properties

In this work, a series of fluorine‐functionalized polysulfone (F‐PSU) copolymers with intrinsic low dielectric constants (low ε) are reported, which are derived from the polycondensation reaction of 4,4′‐dichlorophenyl sulfone with bisphenol A and bisphenol F (BPF) compounds. The resulting F‐PSU copolymers show high glass transition temperatures (T_g) varying from 187 to 201 °C and are thermally stable up to 500 °C under an N₂ atmosphere. The introduction of BPF units into the PSU copolymers imparts enhanced hydrophobic properties to the F‐PSU films with increased water contact angle values from 66.2° to 93.7°. Moreover, the dielectric constant and dielectric loss of the F‐PSU (sample V) film are as low as 2.2 and 0.003 at 1 kHz, respectively. Interestingly, the dielectric properties are relatively stable to near the glass transition temperature, which is because of the existence of BPF structures in the molecular backbone. Furthermore, the F‐PSU copolymers are soluble in common solvents and can be readily fabricated into flexible transparent films by the spin casting method. © 2020 Society of Chemical Industry     

含芳香氨基酸三肽及其衍生物自由基离子的形成和解离机理研究

铜-配体(L)-三肽组成的三元复合物［Cu(L)M］²⁺，其中，L表示4′-氯-2,2′:6′,2″-三联吡啶(缩写为4Cl-tpy)；M表示酪氨酰-甘氨酰-色氨酸(YGW)及其修饰型三肽(CH₃CO-YGW-OCH₃，缩写 Ac-YGW-OMe)。使用该复合物，通过碰撞诱导解离 (collision-induced dissociation, CID)产生两种自由基离子 (［YGW］^·+和［Ac-YGW-OMe］^·+)。采用串联质谱结合密度泛函理论 (density functional theory, DFT)得到气相稳定结构，并研究其气相解离行为。研究结果表明，［YGW］^·+和［Ac-YGW-OMe］^·+的气相解离行为截然不同，［YGW］^·+主要产生［M-CO₂-116］⁺和［M-CO₂］^·+碎片离子；而［Ac-YGW-OMe］^·+在气相中主要产生［M-CH₃OH］^·+碎片离子。推测这两种离子的气相裂解机理分别为：［YGW］^·+羧基上的质子重排到多肽骨架中羰基氧上，经历 C_α-C键的断裂产生［M-CO₂］^·+、断裂色氨酸侧链 C_β-C_γ键产生［M-CO₂-116］⁺离子；［Ac-YGW-OMe］^·+则先经历质子重排到酯基氧上，然后经过C-O酯键的断裂形成［M-CH₃OH］^·+离子。参与重排的质子可能有3个来源：Ac-YGW-OMe中甘氨酸的C_α-H、色氨酸的C_α-H 或C_β-H，该机理有待进一步验证。本研究将为其他类型多肽及衍生物的结构及气相反应机理研究提供参考。     

低比转速压气机轮毂轮缘型线多目标优化设计

对电动增压器用低比转速离心压气机轮毂轮缘进行优化设计。采用NUMECA/FINE Design 3D对压气机进行几何参数化,生成数据库样本,利用人工神经网络和遗传算法对轮毂轮缘型线进行优化,并进行流场分析。仿真结果表明,在设计转速为40000 r/min时,优化后设计点压比和效率分别提高6.59%和3.73%。     

Making Large‐Area Titanium Disulfide Films at Reduced Temperature by Balancing the Kinetics of Sulfurization and Roughening

The synthesis of large‐area TiS₂ thin films is reported at temperatures as low as 500 °C using a scalable two‐step method of metal film deposition followed by sulfurization in an H₂S gas furnace. It is demonstrated that the lowest‐achievable sulfurization temperature depends strongly on the oxygen background during sulfurization. This dependence arises because Ti? O bonds present a substantial kinetic and thermodynamic barrier to TiS₂ formation. Lowering the sulfurization temperature is important to make smooth films, and to enable integration of TiS₂ and related transition metal dichalcogenides—including metastable phases and alloys—into device technology.